Baubeton – dry premixed concrete

BAUBETON

MATERIAL SAFETY DATA SHEET
According to (EU) 830/2015

1. Identification of the Substance/Mixture and of the Company
1.1. Product identifier – BAUBETON
1.2. Application of the substance
Dry cement-sand mixture for repairing and restoration of concrete elements.
1.3. Details of the supplier of the safety data sheet
TERAZID Ltd.
5, 5004 Street, Gara Iskar
1528 Sofia, Bulgaria
tel. +359 2 9799971, office@terazid.com
1.4. Emergency telephone number (EU) 112
UMHATEM “Pirogov” (toxicology) – +3592/9154409; +3592/9154233

2. Hazards Identification
2.1. Classification of the substance or mixture

• Classification in accordance with Regulation (ЕО) 1272/2008 – CLP: The product is classified as „dangerous“.

2.2. Label elements
Hazard pictograms:

Signal word: Danger!

Hazard statements:
H315 – Causes skin irritation.
H318 – Causes serious eye damage.
H335 – May cause respiratory irritation.

Precautionary statements:
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 – IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P305 + P351 + P315 – IF IN EYES: Rinse cautiously with water for several minutes. Get immediate medical advice/attention.
P402 – Store in a dry place.

2.3. Other hazards
Contains portland cement. When reacting with water, it creates an alkaline medium. Does not contain soluble Cr (VI) in a quantity greater than 0.0002% within the period of storage.
For all warnings and recommendations, see Section 15.

3. Composition/information on ingredients
General chemical description: Dry mixture on the basis of portland cement, mineral fillers and modifying additives.
Information of the substances in accordance with CLP 1272/2008/EC

CAS № EINECS №	Name	Concentration (%)	Signal word	H-codes
65997-15-1 266-043-4	Grey cement	20-30	Hazardous	H315, H318, H335

4. First Aid Measures
4.1. Description of the first aid measures
Inhalation – Remove the person to fresh air. If the symptoms continue, immediately seek qualified medical help.
Skin contact – Immediately rinse the area of the contact with plenty of water, then wash it thoroughly with soap and water.
Eye contact – Irrigate with plenty of water for a period of at least 15 minutes and open eyelid. Seek qualified medical help.
Ingestion – Do NOT induce vomiting. Seek qualified medical help.

4.2. Most important symptoms and effects, both acute and delayed
In contact with the eyes: irritation.
In contact with the skin: redness, inflammation.

4.3. Indication of any immediate medical attention and special treatment needed – see p. 4.1.

5. Firefighting Measures
BAUBETON is non-combustible and non-explosive product.

5.1. Extinguishing media
Water mist, water spray – sprayer, dry chemical, foam, carbon dioxide.
Inappropriate means for extinguishing fire – Not known.

5.2. Special hazards, arising from the substance or mixture – None known

5.3. Advice for firefighters – Autonomous respiratory equipment.

6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Gloves, masks, protective clothing for work. Contact with skin and eyes should be avoided

6.2. Environmental precautions
Prevent this product from release into the environment. Measures should be taken to prevent contamination of surface and underground watercourses, soil, as well as entry into drains.
In the event of an accident and/or spill of the product, measures for localization and limitation should be taken. The collected amount of the product should be temporarily stored in special, tightly closed and labeled containers, and afterward transferred to persons holding permits under Article 37 of the Waste Management Act.

6.3. Methods and materials for containment and cleaning up
The spilled amount should be mechanically removed, taking measures to prevent the formation of high concentrations of dust in the air. The amount in the form of dust or unhardened mixture should be rinsed with water and soap.
Collected material should be stored in special, tightly closed and labeled containers and temporarily stored on the territory of the company, then transferred to persons holding a permit under the Waste Management Act (WMA).

7. Handling and Storage
7.1. Precautions for safe handling
The product should be used only according to its main purpose. Do not eat, drink or smoke during work. Avoid formation of dust and ventilate the room regularly. Avoid skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities
It should be stored in ventilated and dry places, in the originally sealed packages. Temperatures lower than 0°C and higher than +50°C should be avoided.
It should be stored separately from food and drinks.

7.3. Specific usage
There is no specific usage. It should be used only according to its main purpose.

8. Exposure Controls/Personal Protection
8.1. Control parameters
Portland cement – permitted level of inhaled powder particles: 5 ppm / 5 mg/m³ air.

8.2. Exposure controls
8.2.1. Respiratory protection – Use a mask preventing inhalation of dust, filter P2.
8.2.2. Skin protection – Avoid skin contact; wear protective gloves.
8.2.3. Eye protection – Avoid eye contact; wear safety glasses.
8.2.4. Common protection – Store away from food, drinks, and animal feed.

9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties

• Appearance – fine powder

• Color – grey

• Odor – none

• pH at 20°C – approximately 7.5

• Density – 1250 kg/m³

• Solubility – insoluble

• Explosive properties – non-explosive

9.2. Other information
No data.

10. Stability and reactivity
10.1. Reactivity – The product reacts with moisture and gets hardened.
10.2. Chemical stability – The product is stable under storage and usage in accordance with the indications.
10.3. Possibility of hazardous reactions – In accordance with section 10.1.
10.4. Conditions to avoid – It should be kept away from moisture during storage and transportation.
10.5. Incompatible materials – No data.

11. Toxicological Information
11.1. Information for the toxicological effects
Toxicological properties of the product are not tested. The product is classified under the conventional method in accordance with Regulation (ЕО) 1272/2008 – CLP. Based on its composition, the product is not expected to have toxic effects under proper usage.

• Ingestion – It is unlikely to cause reaction or long-term effects, but ingestion should be avoided.

• Inhalation – Dust may cause irritation in the nose, throat, and lungs, leading to coughing.

• Skin contact – In combination with heat and sweat, it may cause irritation; not absorbed through the skin.

• Eye contact – The product may cause serious eye damage.

12. Ecological Information
12.1. Toxicity
The product is not expected to be hazardous to the environment (LC50 toxicity in water – not defined). However, in large quantities, it may increase the pH of water and thus become toxic to aquatic organisms under certain conditions.

12.2. Persistence and degradability – No data.
12.3. Bio-accumulative potential – Low potential for bioaccumulation.
12.4. Mobility in soil – Hard product with non-organic origin.
12.5. Results of PBT and vPvB assessment – The product does not meet the criteria of PBT or vPvB.
12.6. Other adverse effects – No data.

13. Disposal Considerations
Product waste, such as residual quantities and packages, should be collected into special, tightly sealed and labeled containers, temporarily stored, and then transferred to entities holding a permit in accordance with Article 37 of the Waste Management Act (publication SG, issue 53, 2012).

Waste code, in accordance with Regulation №2 from 23.07.2014 for Waste Classification:

• 10 13 – Waste from the production of cement, lime, gypsum and items/products made of these materials

• 10 13 14 – Waste concrete and concrete sediment

• 15 01 – Packages

15 01 10* – Packages containing residues of hazardous substances or contaminated with hazardous substances.
Completely empty the packages and dispose of them in accordance with local regulations – at the indicated places for paper waste.

14. Transport Information
The product is not classified as hazardous cargo in accordance with RID, ADR, ADNR, IMDG, IATA-DGR.
It should be transported in accordance with the respective transportation regulations, depending on the transport type, ensuring the safety of the load.

15. Regulatory Information
15.1. Classification and labeling of the product in accordance with Regulation (ЕО) 1272/2008 – CLP (full text of the codes)
GHS Pictograms:

GHS05 GHS07

Signal word: Danger!

Recommendations for danger (N – codes): None

Hazard statements (H – codes):
H315 – Causes skin irritation.
H318 – Causes serious eye damage.
H335 – May cause respiratory irritation.

Precautionary statements (P – codes):
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 – IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P305 + P351 + P315 – IF IN EYES: Rinse cautiously with water for several minutes. Get immediate medical advice/attention.
P402 – Store in a dry place.

15.2. Legislation
National Legislation:
▪ Law of Protection from the Harmful Impact of the Chemical Substances and Preparations
▪ Environmental Protection Law
▪ Health and Safety at Work Act
▪ Ordinance №3 on the minimum requirements for safety and protection of the workers when using personal protective equipment at the workplace
▪ Waste Management Act
▪ Ordinance №2 from 23.07.2014 for Waste Classification
▪ Ordinance on the order and the method of classification, labeling and packaging of chemical substances and preparations

European Legislation:
▪ Regulation (ЕО) 1272/2008 – CLP from 16th December 2008, concerning the classification, labelling and packaging of substances and preparations
▪ Regulation (ЕО) 830/2015 from 28th May 2015

16. Other Information
16.1. Indication of changes
Format in accordance with Regulation (ЕО) 830/2015 from 28th May 2015 amending Regulation № 1907/2006 (REACH) of the European Parliament.

16.2. Training advice
In addition to the training programs on environment and health and safety of the workers, companies need to ensure that their workers read, understand, and apply the requirements of the MSDS.

16.3. Additional information
See the application(s) of exposure scenarios for the following substances:
The basic information of the exposure scenarios of the substances in the mixture are included in points 1, 2, 3, 8, 11, and 12.

16.4. Disclaimer
This safety data sheet and the data inside of it are based on many years of industrial and commercial experience and are fully compliant with the current legislation of the Republic of Bulgaria and the European Union.
This safety data sheet is not intended to guarantee any specific properties and qualities of the product.
The information inside is reliable only when the product is used according to the indicated conditions and applications, specified on the package and/or in the technical literature.
Responsibility for any other use of the product, including use in combination with another product or process, lies entirely with the user.
It is understood that the user is responsible for defining the appropriate precautions and for applying the relevant legislation concerning their own activity.